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Stabitlity of carbocation depends various electronic effects. Least stable carbocation among the following is

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a

O2N−C+H2

b

OHC−C+H2

c

H3CO−C+H2

d

H3C−C+H2

answer is A.

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Detailed Solution

1)Electron withdrawing power of −NO2>−CHO EWG ↓ the stability of carbocation by intensifying the positive charge2)Electron donating power of −OCH3>−CH3 EDG ↑ the stability of carbocation by dispersing the positive charge∴ Stability of 1 < 2 < 4 < 3

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