First slide
Standard EMF of a cell
Question

The standard Potentials at 250 C for the half reactions are given against them below:

Zn2++2e-Zn;E0=-0.762V

 Mg2++2e-Mg;E0=-2.37V

When Zn dust is added to a solution of MgCl2

Easy
Solution

Ezn+2/Zno>EMg+2/Mgo

Spontaneous reduction occurs at Zn electrode.

Spontaneous oxidation occurs at Mg electrode.

Cell reactionMg(s)+Zn(aq)+2Mg(aq)+2+Zn(s)

Zn cannot reduce Mg+2,hence no reaction occurs.

 

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