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Q.

Statement 1 : Aluminium chloride in acidified aqueous solution forms octahedral AlH2O63+  ion.Statement 2 : In AlH2O63+  complex ion, the 3d orbitals of Al are involved and the hybridisation state of Al is sp3d2.

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a

Both Statement 1 and Statement 2 are true.

b

Statement 1 is true and Statement 2 is false.

c

Statement 1 is false and Statement 2 is true.

d

both Statement 1 and Statement 2 are false.

answer is A.

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Detailed Solution

Both are correct. In AlH2O63+ , aluminium is in +3 oxidation state. So,AlH2O63+
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