Statement 1: Anilinium chloride is more acidic than ammonium chloride.Statement 2: Anilinium chloride is resonance stabilised.
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a
Both statements 1 and 2 are correct
b
Statement 1 is correct and statement 2 is incorrect
c
Statement 1 is incorrect and statement 2 is correct
d
Both statements 1 and 2 are incorrect
answer is B.
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Detailed Solution
Aniline is weaker base than ammonium chloride. In NH4CI or aliphatic amines, the non-bonding electron pair of N is localized and is fully available for coordination with a proton.C6H5NH3⊕(stronger acid)→C6H5NH2+H+(weaker-conjugate base)On the other hand, in aniline and other aromatic amines, the non-bonding electron pair is delocalised into benzene ring by resonance.But anilinium ion is less resonance stabilised than aniline