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Statement 1: Boron does not show univalent nature but unipositive nature of thallium is quite stable.

Statement 2: Inert pair effect predominates in Thallium.

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By Expert Faculty of Sri Chaitanya
a
Both statements 1 and 2 are correct
b
Statement 1 is correct and statement 2 is incorrect
c
Statement 1 is incorrect and statement 2 is correct
d
Both statements 1 and 2 are incorrect

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detailed solution

Correct option is A

Both statements are true and the statement 2 is the  explanation of the statement 1.


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The bond dissociation energy of BF bond in BF3 is 646 kJ mol–1 whereas that of CF in CF4 is 315 kJ mol–1. The correct reason for higher B-F bond dissociation energy as compared to that of C-F bond is :

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