Q.

Statement 1 : Crystals of hydrated calcium sulphate gypsum : CaSO4.2H2O are soft and easily cleaved.Statement 2 : Crystals of anhydrous calcium sulphate (anhydride : CaSO4) are very hard and very difficult to cleave.

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a

Both Statement 1 and Statement 2 are true .

b

Statement 1 is true and Statement 2 is false.

c

Statement 1 is false and Statement 2 is true.

d

Both  Statement 1 and Statement 2 are false.

answer is A.

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Detailed Solution

Within the Ca2+/SO42− layers, the ions are held together by strong electrovalent bonds. But these separated Ca2+/SO42− layers are linked by relative weak H - bond. The weakest H - bonds link SO42− ions in the intermediate region. Consequently, the gypsum can be readily cleaved and stretched along the layer of water molecules.Anhydride has a completely ionic structure involving only Ca2+ and SO42−  ions.
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Statement 1 : Crystals of hydrated calcium sulphate gypsum : CaSO4.2H2O are soft and easily cleaved.Statement 2 : Crystals of anhydrous calcium sulphate (anhydride : CaSO4) are very hard and very difficult to cleave.