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Q.

Statement A: Ecello=0 for a chloride ion concentration cell.Statement B: For this concentration cell where Ecell=RTnFln⁡[Cl−]LHS[Cl−]RHS

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a

Both Statement A and Statement B are true

b

Both Statement A and Statement B are true

c

Statement A is true but Statement B is false.

d

Statement A is false but Statement B is true.

answer is A.

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Detailed Solution

Pt,Cl2|Cl−(aq)||Cl−(aq)|Cl2(g),Pt.Anode: 2Cl−→Cl2+2e− (R.H.S.)Cathode: Cl2+2e−→2Cl−(L.H.S.)Ecell=RTnFln⁡[Cl−]LHS[Cl−]RHSEcell=-RTnFln⁡[Cl−]RHS[Cl−]LHS
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