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Q.

Statement 1 : Fe + HCI is preferred as a reagent in the oxidation of nitroalkanes to alkanamines.Statement 2 : Iron scrap and HCI is preferred in the reduction reaction of nitrobenzene.

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a

Both statements 1 and 2 are correct

b

Both statements 1 and 2 are incorrect

c

Statement 1 is correct statement 2 is incorrect

d

Statement 1 is incorrect statement 2 is correct

answer is D.

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Detailed Solution

Reduction of nitro compounds with Fe scrap and HCI is : preferred because FeCl2 formed gets hydrolysed to release HCl during the reaction.Thus, only a small amount of HCl is required to initiate the reaction.
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