Statement 1: Formic acid reduces mercuric chloride to mercurous chloride on heating, while acetic acid does not.Statement 2: Formic acid is stronger acid than acetic acid.

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Both statements 1 and 2 are correct

Statement 1 is correct and statement 2 is incorrect

Statement 1 is incorrect and statement 2 is correct

Both statements 1 and 2 are incorrect

answer is A.

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Detailed Solution

Formic acid behaves as reducing agent as it is oxidised to an unstable acido carbonic acid, which decomposes into CO2 and H2O.HCOOH+2HgCl2⟶ΔHg2Cl2+CO2+2HClHCOOH+2Hg2Cl2⟶CO2+2HCl+2Hg (Black) Acetic acid remains unaffected by mercuric chloride, and does not show reducing properties.

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