Q.
Statement I : Ammonia is highly soluble in water, solubility of other hydrides of 15th group is very lessStatement II : Ammonia can form H-bonds with water , other hydrides of 15th group cannot involve in H-bonding
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a
Both (I) & (II) are True
b
(I) is true & (II) is false
c
(I) is false & (II) is True
d
Both (I) & (II) are false
answer is A.
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Detailed Solution
Covalent compounds like NH3, HF, lower alcohols , lower carboxylic acids, H2O2 are capable of forming intermolecular H-bonding with water.Thus they all are soluble in water.PH3,AsH3,SbH3 and BiH3 cannot form H-bonds with water becauseX-H bond in them is less polar due to large size and lesser electronegativity of the central atom;
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