Q.

Statement I : – C – Cl bond is stronger than Cl – Cl bondStatement II : C – H bond is stronger than C – Cl bond

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a

Statement I and II are true

b

Statement I is true, statement II is false

c

Statement I is false, statement II is true

d

Statement I and II are false

answer is A.

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Detailed Solution

Bond enthalpy of C–H>C–C>C–Cl>Cl–Cl ; ;Bond is very weak because of the repulsions between lone pairs of adjacent chlorine atoms.Size of H-atom <  size of C-atom(both these atoms do not possess a lone pair.); Bond enthalpy of H-H > C-H >C-CIn general Bond enthalpy ∝1size of atoms involved in bonding
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