Q.

Statement I : Carboxylic acid is weaker acid than phenol.Statement II : Phenoxide ion has more resonating structures than carboxylate ion.

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a

Statement I and Statement II both are correct

b

Statement I is correct and Statement II  is incorrect

c

Statement I is incorrect and Statement II  is correct

d

Statement I  and Statement II  both are incorrect

answer is C.

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Detailed Solution

Carboxylate ion is more stable than phenoxide ion;Resonance structures of carboxylate have negative charge delocalized on electronegative oxygen atom moreover they are indistinguishable; Carboxylate ion is more stable;Resonance structures of phenoxide ion have negative charge delocalized on carbon atom also, they are unequivalent;  Phenoxide ion is less stable;Phenols are less acidic than carboxylic acids;
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