Statement I : K2CO3  is prepared by Solvay – ammonia processStatement II : CaCl2  is the by product in Solvay-ammonia process

I) Due to high solubility of KHCO3, it cannot be precipitated. Hence K2CO3  cannot be prepared by Solvay – ammonia process;II) In Ammonia – recovery tower of the process2NH4Cl +CaOH2 →  CaCl2+2H2O +2NH3NH3   is recycled, CaCl2 is the by product