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Q.

Statement - I: The lattice energy of superoxide of alkali metals increases with an increase in the size of the metal ionStatement - II: Lattice energy is directly proportional to size of the metal ion

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a

Statement I and II are correct

b

Statement I is incorrect and statement  II is correct

c

Statement - I is correct and Statement - II is incorrect

d

Both statement - I and II are incorrect

answer is C.

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Detailed Solution

Superoxide formula of alkalimetal MO2As the size of metal ↑es the stability of superoxide ion (O2-) by the M+ ion ↑es and hence stability of super Oxide ↑es and hence lattice energy ↑esstability Order: LiO2 < NaO2 < KO2 < RbO2 < CsO2Hint: A large size cation will stablise the large size anion(O2-)In generalStatement - I is correct & statement - II is in correct
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