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Q.

Statement I : At moderate concentrations molar conductivity of KCl is greater than that of CH3COOHStatement II : At moderate concentrations, KCl completely ionizes whereas CH3COOH undergoes incomplete ionisation

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a

Statement I and II are correct

b

Statement I correct and Statement II incorrect

c

Statement - I is incorrect and Statement - II is correct

d

Both statement - I and II are incorrect

answer is A.

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Detailed Solution

aq. KCl is a strong electrolyte and aq CH3COOH is a weak electrolyte.A strong electrolyte completely ionizes even at moderate concentration where as a weak electrolyte cannot completely ionise even at infinite dilution.Thus at moderate concentrations KCl(aq) is a better conductor than CH3COOH(aq).Statement I and II are correct.
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Statement I : At moderate concentrations molar conductivity of KCl is greater than that of CH3COOHStatement II : At moderate concentrations, KCl completely ionizes whereas CH3COOH undergoes incomplete ionisation