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Q.

Statement I: NaCl in water and organic acids in benzene show abnormal molecular mass.Statement II: Abnormal molecular mass is obtained when the substance in the solution undergoes either dissociation or association.

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a

Statement I and Statement II are true.

b

Statement I is true and  statement II is false.

c

Statement I is false and Statement II is true.

d

Statement I and Statement II are false.

answer is A.

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Detailed Solution

In water NaCl dissociates into Na+ and Cl-(a) Observed molecular weight is less than actual molecular weight(b) Observed colligative properties are more than expected(II) acetic acid dimerizes in benzene due to intermolecular hydrogen bonding.  Due to this association ,(a)  Observed molecular weight of CH3COOH is more than actual molecular weight(b)  Observed colligative properties are lesser than expected(I) & (II) are correct
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