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Q.

Statement I ; Reactivity of halogens towards photochemical halogenation of alkanes is F2>Cl2>Br2>I2Statement II ; Ease of replacement of hydrogen in photochemical halogenation of alkanes is 30H>20H>10H

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a

Statements I and II are correct

b

Statement I is correct and statement II is incorrect

c

Statement I is incorrect and statement II is correct

d

Statements I and II are incorrect

answer is A.

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Detailed Solution

(I)…true;(II)….. stability of R3C.>R2C.H>RC.H2 ;This can be explained on the basis of hyperconjugation ;
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Statement I ; Reactivity of halogens towards photochemical halogenation of alkanes is F2>Cl2>Br2>I2Statement II ; Ease of replacement of hydrogen in photochemical halogenation of alkanes is 30H>20H>10H