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Q.

Statement I : Tin in +2 oxidation state is oxidising agent.Statement II : A substance which undergoes oxidation is oxidising agent

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a

Both Statement I and Statement II are true

b

Statement I is true and Statement II is false

c

Statement I is false and Statement II is true

d

Both Statement I and Statement II are false

answer is D.

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Detailed Solution

(1) For IV A group elementsCommon oxidation state is : "+4"C shows :- +4 , -4Si:- +4 [Stable]Ge,Sn  - +2, +4Stable Pb:        -   +2Stable +4→ For Ge,Sn +4 is stable oxidation state hence in +2 oxidation state they acts as reducing agents→ Where as for Pb '+2' oxidation state is stable [due to inert pair effect] hence in +4 oxidation state Pb acts as oxidising agent→ Higher oxidation state is due to involvement of ns and np electronsi.e., Lower oxidation state is due to involvent of only np electroni.e., ns2 np(2) ⇒ +2Higher oxidation state stability dcecreases from top to bottomGe+4>Sn+4>Pb+4 Stability order Ge+4
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