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Statement 1 : The increase in compressibility factor with increasing pressure is due to a.Statement 2 : Z=1+bPRT for real gases can be obtained by neglecting a/V2 term in vanderWaals equation.

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a

Both Statement 1 and Statement 2 are true .

b

Statement 1 is true and Statement 2 is false.

c

Statement 1 is false and Statement 2 is true.

d

Both Statement 1 and Statement 2 are false.

answer is C.

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Detailed Solution

At high pressure, a(tells about attractions) is negligible.Now the Vanderwaal's equation isP(V-b)=RT PV-Pb=RT PVRT=1+PbRT Z=1+bPRT.

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Statement 1 : The increase in compressibility factor with increasing pressure is due to a.Statement 2 : Z=1+bPRT for real gases can be obtained by neglecting a/V2 term in vanderWaals equation.