Q.

Statement 1: m-Methoxyaniline (m-anisidine) is a weaker base than p-methoxyaniline (p-anisidine).Statement 2: At m-position, methoxy group can exert only +R-effect but not –I-effect.

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a

Both statements 1 and 2 are correct

b

Statement 1 is correct and statement 2 is incorrect

c

Statement 1 is incorrect and statement 2 is correct

d

Both statements 1 and 2 are incorrect

answer is B.

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Detailed Solution

At m-position, methoxy group can exert only –I effect but not +R effect.
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Statement 1: m-Methoxyaniline (m-anisidine) is a weaker base than p-methoxyaniline (p-anisidine).Statement 2: At m-position, methoxy group can exert only +R-effect but not –I-effect.