Q.

Statement 1 : Order of basicity of amines in gaseous phase is NH3 > primary amine>secondary amine > tertiary amine.Statement 2 : In gaseous phase the basic nature of aliphatic amine increases with the increase in number of alkyl groups.

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a

Both statements 1 and 2 are correct

b

Both statements 1 and 2 are incorrect

c

Statement 1 is correct and statement 2 is incorrect

d

Statement 1 is incorrect and statement 2 is correct

answer is D.

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Detailed Solution

Order of basicity of amines in gaseous phase follows the order: Tertiary amine > secondary amine > primary amine > NH3 The basic nature of aliphatic amines increases with increase in the number of alkyl groups (in gaseous phase).
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Statement 1 : Order of basicity of amines in gaseous phase is NH3 > primary amine>secondary amine > tertiary amine.Statement 2 : In gaseous phase the basic nature of aliphatic amine increases with the increase in number of alkyl groups.