Statement 1: PhN⊕2BrΘ is more acidic than NH4Br.Statement 2: PhNH3⊕ (anilinium ion) is resonance stabilised.

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Both statements 1 and 2 are correct

Statement 1 is correct and statement 2 is incorrect

Statement 1 is incorrect and statement 2 is correct

Both statements 1 and 2 are incorrect

answer is B.

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Detailed Solution

NH3 is a stronger base than aniline, therefore, the conjugate acid of aniline (i.e., PhN⊕H2) is more acidic than the conjugate acid of NH3 (i.e., N⊕H3 ion). But anilinium ion is less resonance stabilised than aniline

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