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Q.

Statement 1: Recent convention to represent KP is dimensionless.Statement 2 : The standard state of pure gas is 1 bar and the partial pressure of reactants and products measured with respect to this standard are used to determine KP for the equilibrium.A(g) + 2B(g) → C(g)

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a

Both Statement 1 and Statement 2 are true.

b

Statement 1 is true and statement 2 is false.

c

Statement 1 is false and Statement 2 is true.

d

Both statement 1 and Statement 2 are false.

answer is A.

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Detailed Solution

Let partial pressure of reactants and products are a, b, c bar respectively with respect to standard state, thenA(g) + 2B(g) → C(g)PA' = a bar1 bar=1Similarly, PB' = b and PC' = 0Thus, KP= ca × b2 is dimensionless.

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Statement 1: Recent convention to represent KP is dimensionless.Statement 2 : The standard state of pure gas is 1 bar and the partial pressure of reactants and products measured with respect to this standard are used to determine KP for the equilibrium.A(g) + 2B(g) → C(g)