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Q.

Statement 1 : In the redox reaction8H+aq + 4NO3- + 6 Cl- + Sn(s) →  SnCl62- + 4NO2 + 4H2Othe reducing agent is Sn(s).Statement 2 : In balancing half-reaction, S2O3-2 → S(s) , the number of electrons added on the left is 4.

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a

Both Statement 1 and Statement 2 are true.

b

Statement 1 is true and Statement 2 is false.

c

Statement 1 is false and Statement 2 is true.

d

both Statement 1 and Statement 2 are false.

answer is A.

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Detailed Solution

Sn 0 → +4It undergoes oxidation, so it is the reducing agent.S2O3-2 +6H++ 4e-  →   2S +  3H2O
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Statement 1 : In the redox reaction8H+aq + 4NO3- + 6 Cl- + Sn(s) →  SnCl62- + 4NO2 + 4H2Othe reducing agent is Sn(s).Statement 2 : In balancing half-reaction, S2O3-2 → S(s) , the number of electrons added on the left is 4.