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Statement-I: All P-CI bonds in PCI5 are equal in length.

Statement-II: In vapour state PCl5 (PCI4)+ (PCI6) .

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By Expert Faculty of Sri Chaitanya
a
Both statement-I and statement-II are correct
b
Statement-I is correct and statement-II is incorrect
c
Statement-I is incorrect and statement-II is correct
d
Both statement-I and statement-II are incorrect

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detailed solution

Correct option is D

Both (A) and, (R) are false. PCl5 exists as (PCl4)+ (PCl6)– in solid state. in vapour form it exists as trigonal bipyramidal molecule with two axial P-Cl bonds equal in length and larger than other three equatorial P—Cl bonds.


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