Statement-I : Ammonolysis of excess alkylhalide in a sealed tube at 373 K is the best method to prepare 1° amines.Statement-II : Excess ammonia with alkyl halide at 373 K gives 1° amine as major product
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a
Both statements I and II are correct
b
Statement-I is correct and statement-II is incorrect
c
Statement-I is incorrect and statement-II is correct
d
Both statements I and II are incorrect
answer is C.
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Detailed Solution
I) Ammonolysis of alkyl halide gives a mixture of 1° amine, 2° amine, 3° amine and a 4° salt. This mixture is difficult to separate. This is not a suitable method to prepare 1° amine.R-X(Excess)→-HXNH3R-NH2→-HXR-XR2NH→-HXR-XR3N→ RXR4N+X-;II) R-X+NH3excess→R-NH2major+HX