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Q.

Statement-I : Basic strength of aniline is less than that of acetanilideStatement-II : Lone pair electrons of nitrogen atom are less available for donation in acetanilide than in aniline.

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a

Both statements  I and II are correct

b

Statement-I is correct and statement-II is incorrect

c

Statement-I is incorrect and statement-II is correct

d

Both statements  I and II are incorrect

answer is C.

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Detailed Solution

In acetanilide, the lone pair is not only delocalized on benzene ring but also on -COR group.∴ Basic strength of Acetanilide < Aniline
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