statement(I): Bi+5 salts are very good oxidising agentsstatement(II): Bismuth is more stable in +3 state than in +5 state
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a
Both (I) & (II) are true
b
(I) is true & (II) is false
c
(I) is false & (II) is true
d
Both (I) & (II) are false
answer is A.
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Detailed Solution
Due to Lanthanoid contraction , size increases from Sb to Bi is smallIn 'Bi' nuclear attraction over outermost electrons is more. Thus the paired 'ns' electrons are reluctantto uncouple and participate in bonding . Due to this reason 'Bi' shows an ox. state '+3' (corresponding to ground state)And it is unstable in higher ox. state(+5)Compounds of 'Bi' in '+5' state (except BiF5) are unstable and undergo reduction to form stable compounds with '+3' state