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Q.

Statement-I : The blue precipitate formed by the action of K4FeCN6  on  Fe3+ and by that of K3FeCN6  on  Fe2+  have the same composition.Statement-II : FeCN63− oxidises  Fe2+  to  Fe3+ and itself gets reduced to FeCN64−  Correct relation is

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a

Both are correct statements and statement –II  is correct explanation for statement-I

b

Both are correct statements and statement –II  is  not correct explanation for statement-I

c

Statement –I is correct but statement –II is false

d

Statement –I is incorrect but statement – II is correct

answer is A.

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Detailed Solution

In both case complex formed is Fe4Fe(CN)63
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