Statement-I : The blue precipitate formed by the action of K4FeCN6 on Fe3+ and by that of K3FeCN6 on Fe2+ have the same composition.Statement-II : FeCN63− oxidises Fe2+ to Fe3+ and itself gets reduced to FeCN64− Correct relation is

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Both are correct statements and statement –II is correct explanation for statement-I

Both are correct statements and statement –II is not correct explanation for statement-I

Statement –I is correct but statement –II is false

Statement –I is incorrect but statement – II is correct

answer is A.

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Detailed Solution

In both case complex formed is Fe4Fe(CN)63

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