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Q.

Statement-I: In C2 vapours, the bond order is two where both the bonds are pi bonds.Statement-II: Formal charge on terminal nitrogen atom of :N..=N=O..:  is “-1”.

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a

Both statements I and II are correct

b

Statement-I is correct and statement-II is incorrect

c

Statement-I is incorrect and statement-II is correct

d

Both statements I and II are incorrect

answer is A.

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Detailed Solution

I) C2  .   .   .KK'σ2s 2σ2s*2π2px2π2py2Bond  order=8−42=2;Both the bonds are pi bonds because there are four electrons in two pi bonding molecular orbitals.II) :N..=N=O..:Formal charge = Number of electrons in free state - number of electrons of lone pairs - number of bondsFormal charge on terminal nitrogen = 5 - 4 - 2 = -1
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