Statement-I : Order of the reaction cannot be negativeStatement-II : Saponification is a second order reaction.
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a
Both statements I and II are correct
b
Statement-I is correct and statement-II is incorrect
c
Statement-I is incorrect and statement-II is correct
d
Both statements I and II are incorrect
answer is C.
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Detailed Solution
I) In some reactions when concentration of reactant increass then the rate of reaction decreases. In such cases the order of reaction is negative.Ex: - Concentration of reactant is doubled, rate becomes half the original rate.rate = KCn½ = 2xX = -1order is -1.II) RCOOR + NaOH → RCOONa + ROH is saponification. Hydrolysis of ester in alkaline medium is two.rate = K[ester] [alkali].