The statements regarding Diborane arei) Diborane contains 2-centred - 3-electron bondsii) B - H bond is formed by sp3–s overlappingiii) It contains two coplanar BH2 groupsThe correct statements in above are
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a
i and ii are correct
b
ii and iii are correct
c
i and iii are correct
d
ii is only correct
answer is B.
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Detailed Solution
In diborane each B atom undergoes sp3 hybridisation ,it contains two B-H-B bridges . Each bridge bond is formed by overlapping of one "B"sp3 hybrid orbital with one electron, hydrogen s-orbital with one electron and another boron sp3 hybrid orbital without electron .That is the bridge head bond is a electron deficient three centre two electron bond .The number of atoms involved in bridged bonds in one diborane molecule is four.
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The statements regarding Diborane arei) Diborane contains 2-centred - 3-electron bondsii) B - H bond is formed by sp3–s overlappingiii) It contains two coplanar BH2 groupsThe correct statements in above are