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The stepwise formation of CuNH342+ is given below Cu2++NH3⇄K1CuNH32+CuNH32++NH3⇌K2CuNH322+CuNH322++NH3⇌K3CuNH332+CuNH322++NH3⇌K1CuNH342+The value of stability constants K1, K2, K3 and K4 are 104, 1.58 × 103, 5 × 102 and 102 respectively. The overall equilibrium constants for dissociation of CuNH342+ is x×10−12.The value of x is ________. (Rounded off to the nearest integer).

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Detailed Solution

CuNH342+⇌Cu2++4NH3K=1K1K2K3K4=1104×1.58×103×5×102×102=1.26×10-12=1.26

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The stepwise formation of CuNH342+ is given below Cu2++NH3⇄K1CuNH32+CuNH32++NH3⇌K2CuNH322+CuNH322++NH3⇌K3CuNH332+CuNH322++NH3⇌K1CuNH342+The value of stability constants K1, K2, K3 and K4 are 104, 1.58 × 103, 5 × 102 and 102 respectively. The overall equilibrium constants for dissociation of CuNH342+ is x×10−12.The value of x is ________. (Rounded off to the nearest integer).