First slide

Stability of complexes

Question

The stepwise stability constants of a tetrahedral complex, ${ML}_{4}$ are $10^{5}, 10^{3}, 10^{2} and 10$ respectively. The overall instability constant(dissociation constant) for the complex is

Moderate

Solution

$Overall stability constant (K) = K_{1} \times K_{2} \times K_{3} {xK}_{4} = 10^{11}; Overall instability constant (β) = \frac{1}{K}; = 10^{- 11};$

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