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Q.

A sulphate of metal on heating evolves two gases and an oxide. One of two gas turns K2Cr2O7 paper Green while other gas forms a trimmer without having S-S bond and oxide on treatment with conc. HCl forms a Lewis acid which exists in a dimer. Thus, metal sulphate is

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a

Al2SO43

b

Fe SO4

c

K2SO4

d

MgSO4

answer is B.

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Detailed Solution

i 2FeSO4→Fe2O3+SO2+SO3SO2 Can convert K2Cr2O7 to green Cr2SO43,SO3forms trimmer without S-S bond.ii Fe2O3+6HCl→2FeCl3+3H2O
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