Q.

Sulphurous acid H2SO3 has ka1=1.7×10−2 and ka2=6.4×10−8 . The pH of 0.588​M  H2SO3 is ______ (round off the Nearest Integer)

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answer is 1.

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Detailed Solution

ka1>>ka2H2SO3⇌H++HSO3− C(1−α) Cα CαKa1=Cα21−α H+=Cα=0.092∴PH=−log⁡(0.092) =1.036≅1
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