In the system,CaF2s⇌Ca+2 aq + 2 F- aq , on increasing the concentration of Ca2+ions 4 times their initial value will causethe equilibrium concentration of F-ions to change
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a
14of the initial value
b
12of the initial value
c
2 times the initial value
d
4 times the initial value
answer is B.
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Detailed Solution
K1=Ca+2F-2; Let Ca+2=F-=1M; K1=1; K2=4 × x2,but KC remains constant 4x2 = 4× x2, x2 =14, x=12To keep Kc constant , the concentration of F- should be made 12 of its initial value.