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Q.

At a temperature T, a compound AB4(g) dissociates as 2AB4(g)  ⇌    A2(g) + 4B2(g) with a degree of dissociation x, which is small compared with unity. The expression of KP in terms of x and total pressure P is

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a

8P3x5

b

256P3x5

c

4Px2

d

None of these

answer is A.

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Detailed Solution

2AB4(g)  ⇌    A2(g) + 4B2(g);    ∑ n =1 + 3x2=11 -  x                  x2            2x               1 - x ≃ 1KP = x2 P 2x1 × P4P2 = 8 P3x5
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At a temperature T, a compound AB4(g) dissociates as 2AB4(g)  ⇌    A2(g) + 4B2(g) with a degree of dissociation x, which is small compared with unity. The expression of KP in terms of x and total pressure P is