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The tendency to form monovalent compounds among the Group 13 elements is correctly exhibited in :

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By Expert Faculty of Sri Chaitanya
a
B
b
Tl
c
Tl≈In
d
B≈Al≈Ga≈In≈Tl

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detailed solution

Correct option is A

Monovalent Compounds of 13th Group indicate stability of +1 oxidation state.Down the group stability of “+1” Oxidation state increases due to inert pair effect.Tl+1  is most stable but Tl+3  is unstable∴  Stability of monovalent compounds follow the order B < Al < Ga  <  In  <  Tl


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The bond dissociation energy of BF bond in BF3 is 646 kJ mol–1 whereas that of CF in CF4 is 315 kJ mol–1. The correct reason for higher B-F bond dissociation energy as compared to that of C-F bond is :

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