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Q.

There is no ring strain in cyclohexane, but cyclobutane has an angle strain of 9° 44' .If ΔHc∘ of cyclohexane per (CH2) group is 660 kJ mol-1 and ΔHc∘ of cyclobutene is 2744 kJ mol-1, what is the?it g strain in kJ mol-1 of cyclobutene?

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a

-104

b

104

c

- 2084

d

2084

answer is B.

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Detailed Solution

Ring strain : ≡ΔHc∘ of cyclobutane −4×ΔHc∘ of per CH2group of cyclohexane) : 2744 - (4 x 660)= 104 kJ mol-1
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There is no ring strain in cyclohexane, but cyclobutane has an angle strain of 9° 44' .If ΔHc∘ of cyclohexane per (CH2) group is 660 kJ mol-1 and ΔHc∘ of cyclobutene is 2744 kJ mol-1, what is the?it g strain in kJ mol-1 of cyclobutene?