Thermal stability of MCO3 is in order
BeCO3<MgCO3<CaCO3<SrCO3<BaCO3
MgCO3<BeCO3<CaCO3<SrCO3<BaCO3
CaCO3<SrCO3<BaCO3<BeCO<MgCO3
BaCO3<SrCO3<CaCO3<MgCO3<BeCO3
As the sizes of ions are similar , thermal stability is also more and if the sizes of ions are dissimilar thermal stability is more.