In thermodynamics the P-V work done is given byw=−∫dVPext.For a system undergoing a particular process, the work done is , W=−∫dVRTV−b−aV2This equation is applicable to a
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a
System that satisfies the van der Waals equation of state.
b
Process that is reversible and isothermal.
c
Process that is reversible and adiabatic.
d
Process that is irreversible and at constant isothermal.
answer is A.
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Detailed Solution
For 1 mole Vander Waal's gasP=RTV−b−aV2If Pext = P, means process is reversible. For Vander waal gas, expression is correct for all reversible process
In thermodynamics the P-V work done is given byw=−∫dVPext.For a system undergoing a particular process, the work done is , W=−∫dVRTV−b−aV2This equation is applicable to a