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Q.

In thermodynamics the P-V work done is given byw=−∫dVPext.For a system undergoing a particular process, the work done is , W=−∫dVRTV−b−aV2This equation is applicable to a

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a

System that satisfies the van der Waals equation of state.

b

Process that is reversible and isothermal.

c

Process that is reversible and adiabatic.

d

Process that is irreversible and at constant isothermal.

answer is A.

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Detailed Solution

For 1 mole Vander Waal's gasP=RTV−b−aV2If Pext = P, means process is reversible. For Vander waal gas, expression is correct for all reversible process
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