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Q.

For tie reversible reaction, N2(g)+3H2(g)⇌2NH3(g) at 500o C the value of K p is 1.44×10-5  when partial pressure is measured in atmospheres. The corresponding value of K c with concentration in mole litre -1, is :

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a

1.44×10-5/(0.082×500)-2

b

1.44×10-5/(8.314×773)-2

c

1.44×10-5/(0.082×773)2

d

1.44×10-5/(0.082×773)-2

answer is D.

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Detailed Solution

kp=kc·(RT)Δng
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For tie reversible reaction, N2(g)+3H2(g)⇌2NH3(g) at 500o C the value of K p is 1.44×10-5  when partial pressure is measured in atmospheres. The corresponding value of K c with concentration in mole litre -1, is :