Q.

Toluene is heated with limited supply of chlorine at high temperature to give ‘X’ as major product. ‘X’ is

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a

o-chloro toluene

b

p-chloro toluene

c

m-chloro toluene

d

Benzyl chloride

answer is D.

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Detailed Solution

Toluene reacts with chlorine in presence of Lewis acid in dark conditions to give o-chloro toluene and p-chloro toluene;It is nuclear halogenation,electrophilic substitution;Toluene reacts with chlorine in presence of light or at high temperature to give benzyl chloride;It is side chain halogenation,free radical substitution;C6H6+Cl2→hν or high TC6H5CH2Cl;The reaction continues further to give benzal chloride and benzo trichloride
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