Q.
Total number of stereo isomers (alkynes only) possible with the formula, C5H8 is equal to ‘X’. Total number of enantiomeric pairs (alkadienes only) possible with the formula, C5H8 is ‘Y’. Sum of X and Y is
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a
1
b
0
c
2
d
3
answer is A.
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Detailed Solution
Total number of alkadienes (structural and stereo) = 8 ;Number of structurally isomeric alkadienes = 6 ;Number of structurally isomeric conjugated alkadienes = 2 ;Number of structurally isomeric cumulative alkadienes = 3 ;Number of structurally isomeric isolated alkadienes = 1 ;Number of structurally isomeric straight chain alkadienes = 4 ;Number of structurally isomeric branched chain alkadienes = 2 ;Number of stereo isomers (alkadienes only) = 4 ;Number of geometrical isomers (alkadienes only) = 2 ;Number of optical isomers (alkadienes only) = 2 ;Number of enantiomeric pairs (alkadienes only) = 1 ;Number of structurally isomeric straight chain pentadienes = 4 ;Number of structurally isomeric branched chain butadienes = 2 ;Number of structurally isomeric branched chain propdienes = 0 ;*Cumulative dienes of the type (XY)C=C=C(XY) or (AB)C=C=C(XY) are dissymmetric.They exhibit optical isomerism ;Ex : 2,3-pentadiene…(XY)C=C=C(XY) type where X = H , Y = CH3 : Total number of alkynes = 3 ;Total number of stereo isomers (alkynes only) = 0 ;Total number of enantiomeric pairs (alkynes only) = 0 ;
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