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Q.

Total vapour pressure of mixture of l mol XPX∘=150 torr) and 2 mol YPy=300 torr  is 240 torr. In this case:

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a

There is a negative deviation from Raoult's law

b

There is a positive deviation from Raoult's law

c

There is no deviation from Raoult's law

d

Can not be decided

answer is A.

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Detailed Solution

PIdealsolution =13×150+23×300=250 ∵PSolution 
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Total vapour pressure of mixture of l mol XPX∘=150 torr) and 2 mol YPy=300 torr  is 240 torr. In this case: