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Q.

For the transition from n = 2→n = 1, which of the following will produce shortest wavelength ?

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a

H atom

b

D atom

c

He+ ion

d

Li2+ ion

answer is D.

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Detailed Solution

1λ=R1n12−1n22Z2 as n1&n2 are constant ∴  λ∝1Z2more the nuclear charge smaller be the λH = Z = 1D = Z = 1   ∴  Li2+have shorter wavelengthHe⊕=Z=2Li2+=Z=3
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