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Q.

Two liquids are mixed together to form a mixture which boils at same temperature and their boiling point is higher than the boiling point of either of them so they shows.

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a

no deviation from Raoult's law

b

positive deviation from Raoult's law

c

negative deviation from Raoult's law

d

positive or negative deviation from Raoult's lass depending upon the composition

answer is C.

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Detailed Solution

If force of attraction between A and B (solvents) is higher than that between A and A or B and B, then there is decrease in vaporization. Thus, higher temperature (i.e. boiling point) is required to convert liquids into vapour state. This is a case of negative deviation from Raoult's law.
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Two liquids are mixed together to form a mixture which boils at same temperature and their boiling point is higher than the boiling point of either of them so they shows.