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Q.

Two liters of N, at 0°C and 5 atm pressure is expanded isothermally against a constant external pressure of 1 atm until the pressure of gas reaches 1 atm. Assuming gas to be ideal, calculate work of expansion.

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answer is 810.10 JOULE..

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Detailed Solution

Since the external pressure is greatly different from the pressure of N2 and thus, process is irreversible.

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Two liters of N, at 0°C and 5 atm pressure is expanded isothermally against a constant external pressure of 1 atm until the pressure of gas reaches 1 atm. Assuming gas to be ideal, calculate work of expansion.