Two solid compounds X and Y dissociates at a certain temperature as follows X(s)⇌A(g)+2B(g);KP1=9×10−3atm3Y(s)⇌2B(g)+C(g);Kp2=4.5×10−3atm3The total pressure of gases over a mixture of X and Y is:
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a
4.5 atm
b
0.45 atm
c
0.6 atm
d
None of these
answer is B.
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Detailed Solution
X(s)⇌A(g)+x2B(g)(2x+2y);KP1=PA⋅PB( total )2Y(s)⇌C(g)Y+2B(g)(2y+2x); KP2=PCPB2 (total) KP1KP2=xy⇒x=2yKp1=x(2x+2y)2